Solid state ¹³C and ¹H MAS NMR investigations of C₆₀(ferrocene‐d₁₀)₂ complex

Article type: Research Article

Authors: Shabanova, E. | Schaumburg, K. | Kamounah, F.S.

Affiliations: CISMI, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK‐2100 Copenhagen, Denmark

Note: [] Corresponding author. Tel: +45 35 32 18 24; Fax: +45 39 27 12 07; E‐mail: f.kamounah@symbion.ki.ku.dk; URL: http:// www.cismi.dk.

Abstract: The article presents NMR investigations of a molecular crystalline material C60(ferrocene‐d10)2, which consists of two highly mobile molecules. 13C and 1H NMR line shapes and T1 relaxation times are discussed and compared with results obtained for the undeuteriated compound. The mobilities of C60 and ferrocene molecules were found to increase in the complex in comparison with the two components as crystalline materials.

Keywords: Molecular crystal, plastic crystal, C[TeX:] $_{60}$, ferrocene, [TeX:] $^{13}$C and [TeX:] $^{1}$H NMR

Journal: Spectroscopy, vol. 17, no. 1, pp. 39-44, 2003