A two-dimensional bismuth coordination polymer with tartaric acid: Synthesis, characterization and thermal decomposition to Bi₂O₃ nanoparticles

Article type: Research Article

Authors: Ahadiat, Ghasem^a | Tabatabaee, Masoumeh^{b; *} | Gholivand, Khodayar^c | Zare, Karim^a | Dušek, Michal^d | Kučeráková, Monika^d

Affiliations: [a] Department of Chemistry Science and Research Branch, Islamic Azad University, Tehran, Iran | [b] Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran | [c] Department of Chemistry, Tarbiat Modares University, Tehran, Iran | [d] Institute of Physics ASCR, v.v.i., Praha 8, Czech Republic

Correspondence: [*] Corresponding author: M. Tabatabaee, Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran. Tel.: +98 353187582; Fax: +98 3538223312; E-mail: tabatabaee@iauyazd.ac.ir.

Abstract: A new two-dimensional (2D) bismuth(III) coordination polymer, {[Bi(μ-C4H4O6)(NO3)(H2O)]. 4H2O}∞ (1), resulted from the hydrothermal reaction of tartaric acid and Bi(NO3)3.5H2O. The compound was characterized by elemental analysis and IR spectroscopy, and by X-ray structure analysis. Compound 1 crystallizes in the orthorhombic space groupP212121. Tartrate as a multidentate ligand bridges four symmetry related bismuth(III) ions in an O,O’ fashion to form an infinite 2D coordination network in the (0 0 1) plane. Thermal decomposition of 1 in the presence of polyethylene glycol led to nano-particles of Bi2O3. Powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to characterize the structure and morphology of the Bi2O3 powders. The XRD pattern confirmed the formation of the α-polymorph of Bi2O3.

Keywords: Bismuth coordination polymer, tartrate ligand, Thermal decomposition, α-Bi₂O₃ nanoparticles

DOI: 10.3233/MGC-160216

Journal: Main Group Chemistry, vol. 16, no. 1, pp. 7-16, 2017