Synthesis and Characterization of Dichloro (8-quinolylamido)antimony(III) and 8-Aminoquinolinium Catena-poly[{dichloroantimonate(III)}-μ-dichloro]

Article type: Research Article

Authors: Jones, Cameron | Raston, Colin L. | Smith, Graham

Affiliations: Department of Chemistry, University of Wales, Swansea, Singleton Park, Swansea, SA2 8PP, Wales | Department of Chemistry, Monash University, Clayton, Victoria, 3168, Australia | Department of Chemistry, Queensland University of Technology, P.O. Box 2434, Brisbane, QLD, 4001, Australia

Note: [] Corresponding Author

Note: [] Corresponding Author

Abstract: Slow diffusion of 8-aminoquinoline (H2NQ) into an ethereal solution of SbC13 affords the title compounds [Sb(HNQ)Cl2] and [H3NQ]+ [SbCl4]−. The X-ray crystal structure of the latter reveals discrete cationic units with the anionic units making up an infinite polymeric chain containing chloride bridges.

DOI: 10.1080/13583149612331338667

Journal: Main Group Chemistry, vol. 1, no. 3, pp. 353-357, 1996