Non-destructive and Quantitative Investigation of Jingdezhen Blue and White Porcelains Using EDXRF

Article type: Research Article

Authors: Yu, K. N. | Miao, J. M.

Affiliations: Department of Physics and Materials Science, City University of Hong Kong, Hong Kong | Department of Science and Technology, The Palace Museum, Beijing, People's Republic of China

Abstract: The fabrication of the calibration source is a critical part for the non-destructive and quantitative investigation of blue and white porcelains using EDXRF. In order to minimize the effects on the results due to the matrix difference between the samples and the calibration source, broken porcelain pieces of the Ming and Qing dynasties with matrix conditions similar to those of the measured samples are used directly as calibration sources. The 13 trace elements, viz. Ti, Mn, Fe, Co, Ni, Cu, Zn, Ga, Pb, Rb, Sr, Y, and Zr, have been quantitatively measured for 20 imperial blue and white porcelains of the Qing dynasty and for 11 contemporary Jingdezhen porcelains. The data are then analyzed by the principal component analysis method. The clustering of the data and the identification of the porcelains are then investigated.

DOI: 10.3233/XST-1996-6204

Journal: Journal of X-Ray Science and Technology, vol. 6, no. 2, pp. 167-171, 1996