Affiliations: School of Environmental Science and Engineering, Pohang University of Science and Technology, Pohang, Kyoungbuk, Republic of Korea | Department of Chemistry, Wilfrid Laurier University, Waterloo, Ontario, Canada | Environmental Research Department, Research Institute of Industrial Science and Technology, Pohang, Kyoungbuk, Republic of Korea
Abstract: This study examines the effect of flue gas components on the oxidation of gaseous elemental mercury (Hg0) to HgO and HgCl2 via pulsed corona discharge (PCD), where the reaction temperature was set to 90°C and the gas stream consisting of 3% H2O and 10% O2 in N2 was mixed with 45 μg m−3 Hg0, 108 ppm NOx, 80 ppm HCl, 200 ppm SO2 and 470 ppm NH3. It has been observed that O2 and HCl components in the gas stream act as oxidizing precursors through the generation of oxidizing species (O, O3, Cl and Cl2 ) in the PCD process. The presence of NO directly hampers Hg0 oxidation to HgO due to preferential reaction of NO with O and O3. In contrast, the presence of SO2 indirectly influences the oxidation of Hg0 to HgCl2 through the fast reaction of SO2 with OH radical, resulting in consuming OH radicals which are partially responsible for the formation of chlorine species, i.e. Cl and Cl2. It has been also found that NH3 component significantly hinders the oxidation of Hg0 to HgCl2 through the fast acid–base reaction with HCl.
