X-ray crystal structure and spectral analyses of nonlinear optical L-lysinium trichloroacetate single crystals

Article type: Research Article

Authors: Raghavalu, Thenneti | Mathivanan, V. | Gokul Raj, S. | Ramesh Kumar, G. | Mohan, R. | Suriya Kumar, K. | Kovendhan, M. | Varghese, Babu

Affiliations: Department of Physics, Presidency College, Chepauk, Chennai 600 005, India | Sophisticated Analytical Instrument Facility, Indian Institute of Technology, Chennai 600 025, India

Note: [] Corresponding author. E-mail: professormohan@yahoo.co.in

Abstract: Single crystal X-ray diffraction analysis was carried out on a new nonlinear optical L-lysinium trichloroacetate single crystal. The crystals were obtained from the combination of aqueous solutions of trichloroacetic acid and L-lysine by slow evaporation. A vibrational spectrum of the crystal was determined using FTIR analysis. Differential scanning calorimetry was used to determine the thermal stability of the compound. UV – vis – NIR spectrum of the compound gives its optical transparency. Powder SHG efficiency of L-lysinium trichloroacetate was also studied using Kurtz-Perry powder SHG measurement.

Keywords: L-Lysinium trichloroacetate, Single crystal, Hydrogen bond, FT-IR, DSC analyses, Second harmonic generation

DOI: 10.1080/10241220701595151

Journal: Main Group Chemistry, vol. 6, no. 1, pp. 1-10, 2007