You are viewing a javascript disabled version of the site. Please enable Javascript for this site to function properly.
Go to headerGo to navigationGo to searchGo to contentsGo to footer
In content section. Select this link to jump to navigation

Synthesis and structure of (η5-C5Me5)Ga→Al(C6F5)3· The first example of a gallium – aluminium bond

Article type: Research Article

Authors: Gorden, John D. | Macdonald, Charles L. B. | Cowley, Alan A. H.

Affiliations: Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-0165 USA

Note: [] Corresponding author. Email: cowley@mail.utexas.edu

Abstract: The reaction of [(η5-C5Me5)Ga]6 with Al(C6F5)3 results in (η5-C5Me5)Ga→Al(C6F5)3 (1), the first compound with a gallium-aluminium donor-acceptor bond. The structure of 1 was determined by single-crystal X-ray diffraction.

Keywords: Gallium, Aluminium, Donor, Acceptor, Structure

DOI: 10.1080/10241220500046018

Journal: Main Group Chemistry, vol. 4, no. 1, pp. 33-38, 2005

Received 22 December 2004
|
Published: 2005
Price: EUR 27.50
Show more