Affiliations: [a] National Key Laboratory of Applied Physics and Chemistry, Shaanxi Applied Physics and Chemistry Research Institute, Xi’an, P. R. China | [b] State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, P. R. China
Correspondence:
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Corresponding authors. Dr. Wen-Chao Tong and Dr. Li Yang, State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China. Tel./Fax: +86 10 68911682; E-mails: wenchao061@126.com; yanglibit@bit.edu.cn.
Abstract: A novel transition metal chelate Cd(SCZ)2Cl2 (SCZ = semicarbazide) was synthesized from a known 1D metal-organic framework (MOF) Cd(SCZ)Cl2 and fully characterized by elemental analysis and FTIR spectroscopy. Then the 1D MOF Cd(SCZ)Cl2 was regained by adding CdCl2 to the chelate Cd(SCZ)2Cl2. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)2Cl2 crystallizes in orthorhombic Pbcn space group. Differential scanning calorimetry (DSC) was applied to assess the thermal decomposition behavior of Cd(SCZ)2Cl2. The non-isothermal kinetics parameters of Cd(SCZ)2Cl2 were calculated by the methods of Kissinger and Ozawa-Doyle, respectively.
