Green synthesis of CuO nanoparticles using Peganum harmala extract for photocatalytic and sonocatalytic degradation of reactive dye and organic compounds

Article type: Research Article

Authors: Fekri, Reza^a | Mirbagheri, Seyed-Ahmad^b | Fataei, Ebrahim^{c; *} | Ebrahimzadeh-Rajaei, Gholamreza^d | Taghavi, Lobat^a

Affiliations: [a] Department of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran | [b] Department of Environmental Engineering, Faculty of Civil Engineering, K.N. Toosi University of Technology, Tehran, Iran | [c] Department of Environmental Science, Ardabil Branch, Islamic Azad University, Ardabil, Iran | [d] Department of Chemistry, Ardabil Branch, Islamic Azad University, Ardabil, Iran

Correspondence: [*] Corresponding author: Ebrahim Fataei, Department of Environmental Science, Ardabil Branch, Islamic Azad University, Ardabil, Iran. E-mail: ebfataei@iauardabil.ac.ir.

Abstract:  The present study was performed to evaluate the effectiveness of photocatalytic and sonocatalytic processes for the removal of reactive blue 5 dye and organic compounds of textile effluent in the presence of copper oxide nanoparticles (CuO NPs). CuO NPs were synthesized using Peganum harmala seed extract. The structure of NPs was confirmed using SEM, TEM, XRD, EDX, and FTIR techniques. The tests were carried out in a batch system to assess factors affecting the dye removal efficiency, including contact time, pH, NPs dosage, and initial dye concentration. The experimental results showed that the photocatalytic process (98.42%) produced a higher degradation percentage than the sonocatalytic process (76.16%). While, the dye removal efficiency was not significant in the dark conditions (without UV or US waves). The maximum removal of reactive blue 5 dye under photocatalytic and sonocatalytic conditions occurred at the presence of 0.15 g of CuO NPs and dye concentration of 40 and 60 mg/L, respectively. The kinetic data followed a pseudo-second-order model in both photocatalytic and sonocatalytic processes with a correlation coefficient higher than 0.99. Isotherm studies showed that the Langmuir model was the best isothermal model to describe the adsorptive behavior of CuO NPs in a dark condition. The results obtained from GC-MS showed that the photocatalytic process had a degradation efficiency of over 87% in the removal of organic compounds.

Keywords: Green synthesis, kinetics, photocatalytic degradation, reactive blue 5, sonocatalytic degradation

DOI: 10.3233/MGC-220045

Journal: Main Group Chemistry, vol. 21, no. 4, pp. 975-996, 2022