Preparation and application of one new supramolecular molybdenum oxygen cluster with adsorption of organic contaminants in wastewater

Article type: Research Article

Authors: Wang, Hong-Tao^a | Li, Yuan-Yuan^b | Qiao, Xiu-Ying^b | Lu, Yan-Qi^{a; *} | Niu, Yun-Yin^{b; *}

Affiliations: [a] Department of Pharmacy, Zhengzhou Railway Vocational and Technical College, PR China | [b] College of Chemistry, Zhengzhou University, Henan, P.R. China

Correspondence: [*] Corresponding authors: Yan-Qi Lu, Department of Pharmacy, Zhengzhou Railway Vocational and Technical College, PR China. E-mail: luyanqi@zzrvtc.edu.cn; Yun-Yin Niu, College of Chemistry, Zhengzhou University, Henan 450052, PR China. E-mail: niuyy@zzu.edu.cn.

Abstract: In this paper, one supermolecular compound, namely, p-[C20H18N2O4][Mo8O26]0.5·H2O (1) has been synthesized from 1,4-bis[4-nitrile-pyridine)-N-methylene]phenyldibromide (L1) and (NH4)6Mo7- O24·4H2O by hydrothermal method. The structure has been confirmed through single-crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectra. The adsorption property of compound 1 has bee studied, Thus it’s much important to enrich the types of chemicals.

Keywords: Octamolybdate, hydrothermal synthesis, adsorption

DOI: 10.3233/MGC-210081

Journal: Main Group Chemistry, vol. 20, no. 4, pp. 593-600, 2021