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Article type: Research Article
Authors: Naz, M.Y.a | Irfan, M.b | Shukrullah, S.a; * | Ahmad, I.a | Ghaffar, A.a | Niazi, U. M.c | Rahman, S.b | Jalalah, M.b; d | Alsaiari, M.A.e | Khan, M.K.A.f
Affiliations: [a] Department of Physics, University of Agriculture, Faisalabad, Pakistan | [b] Electrical Engineering Department, College of Engineering, Najran University Saudi Arabia, Najran, Saudi Arabia | [c] Mechanical Engineering Department, National University of Technology, Pakistan | [d] Promising Centre For Sensors and Electronic Devices (PCSED), Najran University Saudi Arabia, Najran, Saudi Arabia | [e] Empty quarter research unit, Chemistry department, college of Science and art at Sharurah, Najran University Saudi Arabia, Najran, Saudi Arabia | [f] Mechanical Engineering Department, College of Engineering, Najran University Saudi Arabia, Najran, Saudi Arabia
Correspondence: [*] Corresponding author: S. Shukrullah, Department of Physics, University of Agriculture, Faisalabad, Pakistan. E-mail: zshukrullah@gmail.com.
Abstract: The conventionally synthesized nano-ferrite materials do not possess bulk properties, generally required for their use in mainstream industry. To make ferrite nanoparticles clinically applicable materials, it is important to have good control over morphology and optical properties of these materials. In this study, low-pressure microwave plasma was used to tailor the structural properties and surface chemistry of manganese ferrite nanoparticles. A facile sol-gel method was used to prepare cubic spinal structures of manganese ferrite nanoparticles. These nanoparticles were exposed to oxygen plasma sustained with a microwave source for improving their magnetic and photocatalytic activities. The techniques like XRD, SEM, PL, UV-Vis DRS, transient photocurrent response and EIS were used to characterize the samples. The plasma treated nanoparticles were used to degraded methyl blue (MB) dye in the solution. The photocatalytic activity showed 85% degradation of MB after 100 min of exposure of visible light. The second part of the paper studied the magnetic properties of the nanoparticles. The saturation magnetization decreased from 0.78 emu/g to 0.68 emu/g after plasma treatment of nanoparticles.
Keywords: Sol-gel method, manganese ferrite, photocatalyst, magnetization, microwave plasma
DOI: 10.3233/MGC-210065
Journal: Main Group Chemistry, vol. 20, no. 3, pp. 423-435, 2021
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