Synthesis, characterization, adsorption and catalytic activity of a polyoxometalate supramolecule templated by arylmethylamine

Article type: Research Article

Authors: Wang, Xiao-Jia | Qiao, Xiu-Ying | Niu, Yun-Yin^{; *}

Affiliations: College of Chemistry, Zhengzhou University, Henan, P. R. China

Correspondence: [*] Corresponding author: Yun-Yin Niu, College of Chemistry, Zhengzhou University, Henan 450001, P. R. China. Tel.: +86 371 67783126; E-mail: niuyy@zzu.edu.cn.

Abstract: A novel supramolecular compound 1 (C6H3) (CH2NH3)2+ (CH2NH2)]2· (β-Mo8O26)·3H2O was constructed under hydrothermal conditions by (NH4)6Mo7O24·4H2O and arylmethylamine cation L1. This compound 1 has been unambiguously characterized by PXRD, IR, and X-ray single crystal diffraction. What’ more, the compound 1 has features of adsorption and catalytic activity.

Keywords: Supramolecule, adsorption, catalytic activity

DOI: 10.3233/MGC-190891

Journal: Main Group Chemistry, vol. 19, no. 3, pp. 187-198, 2020