A new Mo/S/Cu polymeric cluster: Synthesis, structure and properties

Article type: Research Article

Authors: Shu, Zunzhe^a | Wang, Chaohai^b | Li, Yao^b | Du, Haijuan^b | Niu, Yunyin^{b; *}

Affiliations: [a] College of Life Science, Tarim University, Aral City, Xinjiang, China | [b] College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, China

Correspondence: [*] Corresponding author: Yunyin Niu, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P.R. China. E-mail: niuyy@zzu.edu.cn

Abstract: Compound {[MoOS3Cu3Br(μ-bpy)2.5]·0.75DMF}∞ is an isomorphous neutral 3D 4-fold interpenetrating architecture displaying self-interpenetrating feature.sometimes, the compound like the art. All of it have been characterized by single-crystal X-ray diffraction, elemental analysis, IR, TGA, and UV-vis. The results may provide fascinating insights into template effect on the construction of the cluster-based coordination polymers.

Keywords: Cationic templates, supramolecular polymer, self-assembly

DOI: 10.3233/MGC-150184

Journal: Main Group Chemistry, vol. 15, no. 1, pp. 67-74, 2016