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Article type: Research Article
Authors: Qiao, Gui-Ying | Wang, Fu-Rong | Zhu, Yu | Niu, Yun-Yin; *
Affiliations: College of Chemistry and Molecular Engineering, Zhengzhou University, Henan, P. R. China
Correspondence: [*] Corresponding author: Yun-Yin Niu, College of Chemical and Molecular Engineering, Zhengzhou University, Henan 450052, PR China. E-mail: niuyy@zzu.edu.cn.
Abstract: A new supermolecular compound, [C7H10N4][Mo8O26]0.5·H2O has been synthesized from 1,1-bis(imidazole) methane and (NH4)6Mo7O24·4H2O by hydrothermal method. Structural analysis reveals that every asymmetric structure unit of the compound is composed of one [C7H10N4]2+ and half [Mo8O26]4– and one water molecule. Crystal pack of the compound suggests that polyacid anions represent the one-dimensional chain-shaped structure and organic cations parallel the one-dimensional chains. The compound has the characteristics of detection Fe3+, adsorption and catalysis activities.
Keywords: Template effect, octamolybdate, fluorescent probe, adsorption
DOI: 10.3233/MGC-180771
Journal: Main Group Chemistry, vol. 18, no. 3, pp. 291-304, 2019
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