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Iodosylperfluoroalkanes as Reagents for the Preparation of Perfluoroalkyliodonium Salts under Aprotic Conditions

Article type: Research Article

Authors: Zhdankin, Viktor V. | Kuehl, Chris J. | Simonsen, Angela J.

Affiliations: Chemistry Department, University of Minnesota-Duluth, Duluth, Minnesota 55812 USA

Note: [] Corresponding Author

Abstract: Iodosylperfluoroalkanes (CnF2n+1IO, n = 2,3,4,6) were prepared in high yield by mild hydrolysis of [bis(trifluoroacetoxy)iodo]perfluoroalkanes with sodium bicarbonate and ice. Reaction of iodosylperfluoroalkanes with 1,4-bis (trimethylsilyl) benzene in the presence of trimethylsilyltriflate gave the corresponding perfluoroalkyl(ary1) iodonium triflates in 70–83% yield.

DOI: 10.1080/13583149612331338657

Journal: Main Group Chemistry, vol. 1, no. 3, pp. 349-352, 1996

Received 30 October 1995
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Published: 1996
Price: EUR 27.50
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