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Article type: Research Article
Authors: Guerrero, Leticia | Montalvo, Ruben | Rivero, Ignacio A. | Barba, Victor
Affiliations: UACBI y UACQByF, Universidad Autónoma de Nayarit, Ciudad de la Cultura Amado Nervo, Tepic, Nayarit, México | Centro de Graduados e Investigación en Química, Instituto Tecnológico de Tijuana, Tijuana, B.C., México | Centro de Investigaciones Químicas, Av. Universidad, Col. Chamilpa, Cuernavaca, Morelos, México
Note: [] Corresponding author: V. Barba, Centro de Investigaciones Químicas, Av. Universidad 1001, Col. Chamilpa, CP 62209, Cuernavaca, Morelos, México. Tel./Fax: +52 777 3297997, E-mail: vbarba@uaem.mx
Abstract: Two quinazolinediones were crystallized and the molecular structures solved by monocrystal X-ray diffraction analysis. The title compounds include the only variation of the -OMe substituent at orto or meta positions of the aromatic ring. The results were contrasted with the analogous para substituted derivative allowing a complete structural comparison in order to see the substituent effect. The formation of different hydrogen bonding motifs was observed which are relevant to the design of supramolecular assemblies.
Keywords: X-ray crystallography, quinazolinediones, hydrogen bonding
DOI: 10.3233/MGC-120078
Journal: Main Group Chemistry, vol. 11, no. 4, pp. 259-265, 2012
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