Affiliations: Research Center for Eco-Environmental Sciences,
chinese academy of Sciences, Beijing 100085, China. E-mail:
yechm@mail.rcees.ac.cn
Note: [] Corresponding author
Abstract: The hydrolysis kinetics of atrazine in distilled water and leaching
water from soil, and their influence factors were studied by incubation at
35°C and HPLC analysis method in this paper. The kinetic process of
atrazine hydrolysis can be described by the first-order reaction law. The
results showed that the hydrolysis rate constants k in leaching water and
distilled water were 1.606x10^-³/d and 1.055x10^-³/d, respectively;
the half-life of atrazine hydrolysis in distilled water at pH 3, pH 4.5 and pH
8 were 373 days, 522 days and 657 days respectively. The results also showed
that the proton in reaction solution can catalyze the atrazine hydrolysis;
humic acid and NH_4^+ etc. substances in aqueous solution can facilitate
atrazine hydrolysis; rate constants of atrazine hydrolysis with humic acid and
NH_4NO_3 were 2.431x10^-³/d and 1.498x10-³/d respectively which were
2.3 and 1.42 times of control(1.055x10-³/d); anion NO_3^- can inhibit
catalysis of humic acid to atrazine hydrolysis.