Adsorption of chloroacetanilide herbicides on soil (I). Structural influence of chloroacetanilide herbicide for their adsorption on soils and its components

Article type: Research Article

Authors: LIU, Wei-ping | LIU, Hui-jun | ZHENG, Wei | WANG, Qi-quan | LU, Jian-hang

Affiliations: Institute of Environmental Science, Zhejiang University at Yuquan Campus, Hangzhou 310027, China; E-mail: wpliu@mail.hz.zj.cn

Note: [] Corresponding author

Abstract: Adsorption of chloroacetanilide herbicide acetochlor,alachlor, metolachlor and propachlor on soils and soil components was determined, and the structural differences of these herbicides were used to explain the order of sorptivity. Adsorption isotherms for all herbicide-soil combinations conformed to the Freundlich equation, and K_f increased with increasing soil organic carbon content. K_d on soil humic acid was greater than that on clay, but association of humic acid with clay reduced the overall adsorption. On all soils and soil humic acids, herbicide adsorption decreased in the order: metolachlor > acetochlor > propachlor > alachlor. On Ca^2^+-montmorrilonite, the order changed to metolachlor > acetochlor > alachlor > propachlor. FT-IR spectra of herbicide-clay or herbicide-humic acid-clay mixtures showed that H-bonding and charge transfer were the primary interaction pathways between these compounds and the surface of clay or humic acids. The different moieties attached to 2-chloro-acetanilide and their unique arrangement may have influenced the binding mechanisms and thus the sorptivity of these herbicides. This study indicates that the structural difference of pesticides in the same classes may be used as a molecular probe to obtain a better understanding of sorption mechanisms of pesticides on soil.

Keywords: adsorption, chloroacetanilide herbicides, soil, organic matter, clay

Journal: Journal of Environmental Sciences, vol. 13, no. 1, pp. 37-45, 2001